Search results for "Slow rotation"
showing 3 items of 3 documents
Ring transformation of furfural into an unusual bicyclic system: Characterisation and dynamic stereochemistry of 6,7-diethoxycarbonyl-6,7-diaza-8-oxa…
1997
Abstract 2-Formylthiophene and 3-formylindole react with diethyl azodicarboxylate to give simple products derived from reactions on the formyl group whereas 2-formylfuran reacts to give the unexpected bicyclic title compound. 1 H and 13 C NMR studies indicate that this compound undergoes a series of three dynamic conformational changes over the temperature range 50 to −90°C which are ascribed to slow rotation about the exocyclic carbamate bonds and hindered bridge inversion.
Stability of the intrinsic energy vanishing in the Schwarzschild metric under a slow rotation
2014
The linearized Kerr metric is considered and put in some Gauss coordinates which are further {\em intrinsic} ones. The linear and angular 4-momenta of this metric are calculated in these coordinates and the resulting value is just zero. Thus, the global vanishing previously found for the Schwarzschild metric remains linearly stable under slow rotational perturbations of this metric.
Form factors in the 'point form' of relativistic quantum mechanics : single and two-particle currents
2004
Electromagnetic and Lorentz-scalar form factors are calculated for a bound system of two spin-less particles exchanging a zero-mass scalar particle. Different approaches are considered including solutions of a Bethe-Salpeter equation, a ``point form'' approach to relativistic quantum mechanics and a non-relativistic one. The comparison of the Bethe-Salpeter results, which play the role of an ``experiment'' here, with the ones obtained in ``point form'' in single-particle approximation, evidences sizable discrepancies, pointing to large contributions from two-body currents in the latter approach. These ones are constructed using two constraints: ensuring current conservation and reproducing …